| Day One | ||||
| Tuesday 17 September 2013 | ||||
| Manchester United | 4-2 | Leverkusen | 19:45 | |
| Real Sociedad | 0-2 | Shkahtar Donetsk | 19:45 | |
| Copenhagen | 1-1 | Juventus | 19:45 | |
| Galatasaray | 1-6 | Real Madrid | 19:45 | |
| Benfica | 2-0 | Anderlecht | 19:45 | |
| Olympiakos | 1-4 | PSG | 19:45 | |
| Bayern Munich | 3-0 | CSKA Moscow | 19:45 | |
| Viktoria Plzen | 0-3 | Manchester City | 19:45 | |
| Day Two | ||||
| Wednesday 18 September 2013 | ||||
| Schalke | 3-0 | Steaua Bucharest | 19:45 | |
| Chelsea | 1-2 | Basel | 19:45 | |
| Marseille | 1-2 | Arsenal | 19:45 | |
| Napoli | 2-1 | Dortmund | 19:45 | |
| Austria Vienna | 0-1 | Porto | 19:45 | |
| Atletico Madrid | 3-1 | Zenit | 19:45 | |
| Milan | 2-0 | Celtic | 19:45 | |
| Barcelona | 4-0 | Ajax | 19:45 | |
| Day Three | ||||
| Tuesday 1 October 2013 | ||||
| Basel | 0-1 | Schalke | 19:45 | |
| Steaua Bucharest | 0-4 | Chelsea | 19:45 | |
| Arsenal | 2-0 | Napoli | 19:45 | |
| Dortmund | 3-0 | Marseille | 19:45 | |
| Zenit St Petersburg | 0-0 | Austria Vienna | 19:45 | |
| Porto | 1-2 | Atletico Madrid | 19:45 | |
| Ajax | 1-1 | Milan | 19:45 | |
| Celtic | 1-0 | Barcelona | 19:45 | |
| Day Four | ||||
| Wednesday 2 October 2013 | ||||
| Leverkusen | 2-1 | Sociedad | 19:45 | |
| Shakhtar Donetsk | 1-1 | Manchester United | 19:45 | |
| Juventus | 2-2 | Galatasaray | 19:45 | |
| Real Madrid | 4-0 | Copenhagen | 19:45 | |
| PSG | 3-0 | Benfica | 19:45 | |
| Anderlecht | 0-3 | Olympiakos | 19:45 | |
| CSKA Moscow | 3-2 | Viktoria Plzen | 17:00 | |
| Manchester City | 1-3 | Bayern Munich | 19:45 | |
| Day Five | ||||
| Tuesday 22 October 2013 | ||||
| Steaua Bucharest | 1-1 | Basel | 19:45 | |
| Schalke | 0-3 | Chelsea | 19:45 | |
| Marseille | 1-2 | Napoli | 19:45 | |
| Arsenal | 1-2 | Dortmund | 19:45 | |
| Austria Vienna | 0-3 | Atletico Madrid | 19:45 | |
| Porto | 0-1 | Zenit | 19:45 | |
| Celtic | 2-1 | Ajax | 19:45 | |
| Milan | 1-1 | Barcelona | 19:45 | |
| Day Six | ||||
| Wednesday 23 October 2013 | ||||
| Leverkusen | 4-0 | Shakhtar Donetsk | 19:45 | |
| Manchester United | 1-0 | Real Sociedad | 19:45 | |
| Galatasaray | 3-1 | Copenhagen | 19:45 | |
| Real Madrid | 2-1 | Juventus | 19:45 | |
| Anderlecht | 0-5 | PSG | 19:45 | |
| Benfica | 1-1 | Olympiakos | 19:45 | |
| CSKA Moscow | v | Manchester City | 17:00 | |
| Bayern Munich | 5-0 | Viktoria Plzen | 19:45 | |
| Day Seven | ||||
| Tuesday 23 October 2013 | ||||
| Real Sociedad | 0-0 | Manchester United | 19:45 | |
| Shakhtar Donetsk | 0-0 | Leverkusen | 19:45 | |
| Copenhagen | 1-0 | Galatasaray | 19:45 | |
| Juventus | 2-2 | Real Madrid | 19:45 | |
| Olympiakos | 1-0 | Benfica | 19:45 | |
| PSG | 1-1 | Anderlecht | 19:45 | |
| Viktoria Plzen | 0-1 | Bayern Munich | 19:45 | |
| Manchester City | 5-2 | CSKA Moscow | 19:45 | |
| Day Eight | ||||
| Wednesday 23 October 2013 | ||||
| Zenit St Petersburg | 1-1 | Porto | 17:00 | |
| Basel | 1-1 | Steaua Bucharest | 19:45 | |
| Chelsea | 3-0 | Schalke | 19:45 | |
| Napoli | 3-2 | Marseille | 19:45 | |
| Dortmund | 0-1 | Arsenal | 19:45 | |
| Atletico Madrid | 4-0 | Austria Vienna | 19:45 | |
| Ajax | 1-0 | Celtic | 19:45 | |
| Barcelona | 3-1 | Milan | 19:45 | |
| Day Nine | ||||
| Tuesday 26 November 2013 | ||||
| Steaya Bucharest | 0-0 | Schalke | 19:45 | |
| Basel | 1-0 | Chelsea | 19:45 | |
| Dortmund | 3-1 | Napoli | 19:45 | |
| Arsenal | 2-0 | Marseille | 19:45 | |
| Zenit St Petersburg | 1-1 | Atletico Madrid | 17:00 | |
| Porto | 1-1 | Austria Vienna | 19:45 | |
| Celtic | 0-3 | Milan | 19:45 | |
| Ajax | 2-1 | Barcelona | 19:45 | |
| Day Ten | ||||
| Wednesday 27 October 2013 | ||||
| Leverkusen | 0-5 | Manchester United | 19:45 | |
| Shakhtar Donetsk | 4-0 | Real Sociedad | 19:45 | |
| Real Madrid | 4-1 | Galatasaray | 19:45 | |
| Juventus | 3-1 | Copenhagen | 19:45 | |
| Anderlecht | 2-3 | Benfica | 19:45 | |
| PSG | 2-1 | Olympiakos | 19:45 | |
| CSKA Moscow | 1-3 | Bayern Munich | 17:00 | |
| Manchester City | 4-2 | Viktoria Plzen | 19:45 | |
| Day Eleven | ||||
| Tuesday 10 December 2013 | ||||
| Real Sociedad | 0-1 | Leverkusen | 19:45 | |
| Manchester United | 1-0 | Shakhtar Donetsk | 19:45 | |
| Copnehagen | 0-2 | Real Madrid | 19:45 | |
| Olympiakos | 3-1 | Anderlecht | 19:45 | |
| Benfica | 2-1 | PSG | 19:45 | |
| Viktoria Plzen | 2-1 | CSKA Moscow | 19:45 | |
| Bayern Munich | 2-3 | Manchester City | 19:45 | |
| Last 16 | ||||
| Wednesday 11 December 2013 | ||||
| Chelsea | 1-0 | Basel | 19:45 | |
| Schalke | 2-0 | Basel | 19:45 | |
| Marseille | 1-2 | Dortmund | 19:45 | |
| Napoli | 2-0 | Arsenal | 19:45 | |
| Atletico Madrid | 2-0 | Porto | 19:45 | |
| Austria Vienna | 4-1 | Zenit St Petersburg | 19:45 | |
| Milan | 0-0 | Ajax | 19:45 | |
| Barcelona | 6-1 | Celtic | 19:45 | |
| Galatasaray | 1-0 | Juventus | 13:00 | |
| Last 16 | ||||
| Tuesday 18 February 2014 | ||||
| Manchester City | 0-2 | Barcelona | 19:45 | |
| Leverkusen | 0-4 | PSG | 19:45 | |
| Wednesday 19 February 2014 | ||||
| Milan | 0-1 | Atletico Madrid | 19:45 | |
| Arsenal | 0-2 | Bayern Munich | 19:45 | |
| Tuesday 25 February 2014 | ||||
| Zenit St Petersburg | 2-4 | Dortmund | 19:45 | |
| Olympiakos | 2-0 | Manchester United | 19:45 | |
| Wednesday 26 February 2014 | ||||
| Galatasaray | 1-1 | Chelsea | 19:45 | |
| Schalke | 1-6 | Real Madrid | 19:45 | |
| Tuesday 11 March 2014 | ||||
| Atletico Madrid | 4-1 | Milan | 19:45 | |
| Bayern Munich | 1-1 | Arsenal | 19:45 | |
| Wednesday 12 March 2014 | ||||
| Barcelona | 2-1 | Manchester City | 19:45 | |
| PSG | 2-1 | Leverkusen | 19:45 | |
| Tuesday 18 March 2014 | ||||
| Chelsea | 2-0 | Galatasaray | 19:45 | |
| Real Madrid | 3-1 | Schalke | 19:45 | |
| Wednesday 19 March 2014 | ||||
| Manchester United | 3-0 | Olympiakos | 19:45 | |
| Dortmund | 1-2 | Zenit St Petersburg | 19:45 | |
| Quarter Finals | ||||
| Tuesday 1 April 2014 | ||||
| Barcelona | 1-1 | Atletico Madrid | 19:45 | |
| Manchester United | 1-1 | Bayern Munich | 19:45 | |
| Wednesday 2 April 2014 | ||||
| Real Madrid | 3-0 | Dortmund | 19:45 | |
| PSG | 3-1 | Chelsea | 19:45 | |
| Tuesday 8 April 2014 | ||||
| Dortmund | 2-0 | Real Madrid | 19:45 | |
| Chelsea * | 2-0 | PSG | 19:45 | |
| Wednesday 9 April 2014 | ||||
| Atletico Madrid | 1-0 | Barcelona | 19:45 | |
| Bayern Munich | 3-1 | Manchester United | 19:45 | |
| Semi Finals | ||||
| Tuesday 22 April 2014 | ||||
| Atletico Madrid | 0-0 | Chelsea | 19:45 | |
| Wednesday 23 April 2014 | ||||
| Real Madrid | 1-0 | Bayern Munich | 19:45 | |
| Tuesday 29 April 2014 | ||||
| Bayern Munich | 0-4 | Real Madrid | 19:45 | |
| Wednesday 30 April 2014 | ||||
| Chelsea | 1-3 | Atletico Madrid | 19:45 | |
| Final | ||||
| Saturday 24 May 2014 | ||||
| Real Madrid ** | 4-1 | Atletico Madrid | 19:45 | |
* = win on away goals
** = after extra time